Asymmetric synthesis of α,β-epoxysulfones via phase-transfer catalytic Darzens reaction.

DOI Number:

10.1016/j.tet.2007.06.012

Reaction Category:

MOP ID:

MOP_0000671

Educt:

((chloromethyl)sulfonyl)benzene, aldehydes

Product:

(2R)-substituted (3R)-3-(phenylsulfonyl)oxirane

Catalyst:

(9S)-9-hydroxy-6′-methoxy-1-[(2,3,4-trifluorophenyl)methyl]-cinchonanium bromide

Cas No:

949028-87-9

Cas No:

56-54-2