Catalytic Asymmetric Epoxidation of α-Branched Enals.

DOI Number:

10.1021/ja1037935

Reaction Category:

MOP ID:

MOP_0000671

Educt:

2-methylenedec-9-enal, hydrogen peroxide

Product:

(R)-2-(oct-7-en-1-yl)oxirane-2-carbaldehyde

Catalyst:

(8α,9S)-6′-Methoxycinchonan-9-amine with 4-hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin 4-oxide (1:2)

Cas No:

1239467-41-4

Cas No:

130-95-0