Highly Enantioselective Epoxidation of 2‐Methylnaphthoquinone (Vitamin K3) Mediated by New Cinchona Alkaloid Phase‐Transfer Catalysts.

DOI Number:

10.1002/chem.200600993

Reaction Category:

MOP ID:

MOP_0000671

Educt:

2‐Methylnaphthoquinone, sodium hypochlorite

Product:

(1aR,7aS)-1a-methyl-1a,7a-dihydronaphtho[2,3-b]oxirene-2,7-dione

Catalyst:

1-(9-anthracenylmethyl)-10,11-dihydro-6′,9-dihydroxy-(9S)-cinchonanium chloride

Cas No:

945425-86-5

Cas No:

73522-75-5