Highly Diastereodivergent Synthesis of Tetrasubstituted Cyclohexanes Catalyzed by Modularly Designed Organocatalysts
![](https://www.buchler-gmbh.com/wp-content/uploads/Domino-Michael-Addition.jpg)
DOI Number:
10.1002/anie.201404072
Reaction Category:
MOP ID:
MOP_0000561
Educt:
(E)-7-(4-methoxyphenyl)-7-oxohept-5-enal, (E)-5-(2-nitrovinyl)benzo[d][1,3]dioxole
Product:
(1S,2S,3R,4R)-2-(benzo[d][1,3]dioxol-5-yl)-4-(2-(4-methoxyphenyl)-2-oxoethyl)-3-nitrocyclohexane-1-carbaldehyde
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-25-8
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2