Catalytic, Enantioselective Bifunctional Inverse Electron Demand Hetero-Diels− Alder Reactions of Ketene Enolates and o-Benzoquinone Diimides.

DOI Number:

10.1021/ja065754d

Reaction Category:

RXNO ID:

RXNO_0000006

Educt:

N,N'-((1E,2E)-4-benzoylcyclohexa-3,5-diene-1,2-diylidene)dibenzamide, 3-(methylthio)propanoyl chloride

Product:

(S)-(3-((methylthio)methyl)-2-oxo-2,3-dihydroquinoxaline-1,4,6-triyl)tris(phenylmethanone)

Catalyst:

6′-methoxy-(9S)-Cinchonan-9-ol-9-benzoate

Cas No:

60723-45-7

Cas No:

56-54-2