Asymmetric Inverse-Electron-Demand Diels-Alder Reaction of 2-Pyrone and 2, 5-Dienones via HOMO-Activation.

DOI Number:

10.6023/A18040131
Link to literature

Reaction Category:

Cycloaddition | Diels-Alder reaction

RXNO ID:

RXNO_0000006

Educt:

2-Pyrones, 2,5-Dienones

Product:

7-substituted methyl (1R,8R)-3-oxo-8-((3-oxocyclohex-1-en-1-yl)methyl)-2-oxabicyclo[2.2.2]oct-5-ene-4-carboxylate

Catalyst:

(9R)-6′-methoxy-cinchonan-9-amine

Cas No:

287979-82-2

Associated Product from Buchler GmbH:

Quinidine Base

Cas No:

56-54-2