Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation.
DOI Number:
10.1021/jacs.4c00374
Reaction Category:
MOP ID:
MOP_0000479
Educt:
sulfonimidamide, trifluoroethyl trifluoroacetate
Product:
(S)-N-(amino(oxo)(phenyl)-l6-sulfaneylidene)-trifluoroacetamide
Catalyst:
(8α,9R)-6′-methoxy-cinchonan-9-ol diphenylphosphinate (ester)
Cas No:
870283-96-8
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0