Organocatalytic kinetic resolution of racemic secondary nitroallylic alcohols combined with simultaneous desymmetrization of prochiral cyclic anhydrides.
DOI Number:
10.1021/jo501882q
Reaction Category:
Educt:
prochiral cyclic anhydrides, secondary nitroallylic alcohols
Product:
substituted (R)-5-((1-ethoxy-3-nitro-1-oxobut-3-en-2-yl)oxy)-5-oxopentanoic acid
Catalyst:
N-(8α,9S)-cinchonan-9-yl-N′-phenyl-thiourea
Cas No:
1133426-70-6
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2