Asymmetric Intramolecular Rauhut–Currier Reaction and Its Desymmetric Version via Double Thiol/Phase-Transfer Catalysis.
DOI Number:
10.1021/acs.joc.0c01293
Reaction Category:
Educt:
(2E,5E)-1,8-diphenylocta-2,5-diene-1,7-dione
Product:
(R)-2-(2-benzoylcyclopent-2-en-1-yl)-1-phenylethan-1-one
Catalyst:
3,3'-dimercapto-[1,1'-binaphthalene]-2,2'-diol, (8α,9S)-1-[[2′-[[(1,1-dimethylethyl)dimethylsilyl]oxy][1,1′:3′,1′′-terphenyl]-5′-yl]methyl]-9-hydroxy-6′-methoxy-Cinchonanium bromide (1:1)
Cas No:
2483863-20-1
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0