Organocatalytic desymmetrization reactions for the synthesis of axially chiral compounds.
DOI Number:
10.1002/tcr.201800194
Reaction Category:
Educt:
2-acetylcyclopentan-1-one, 1-(2-(tert-butyl)phenyl)-1H-pyrrole-2,5-dione
Product:
(R)-3-((S)-1-acetyl-2-oxocyclopentyl)-1-(2-(tert-butyl)phenyl)pyrrolidine-2,5-dione
Catalyst:
(9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)]bis[10,11-dihydro-6′-methoxy-cinchonan]
Cas No:
149725-81-5
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8