Highly Enantioselective Synthesis of [1,2,4] Triazino [5,4-a] isoquinoline Derivatives via (3+3) Cycloaddition Reactions of Diazo Compounds and Isoquinolinium Methylides.
DOI Number:
10.1021/acs.orglett.2c01122
Reaction Category:
MOP ID:
MOP_0000562
Educt:
diazo compounds, isoquinolinium methylides
Product:
[1,2,4] triazino [5,4-a] isoquinoline derivatives
Catalyst:
(1S,2R,4S,5R)-2-((S)-(hexyloxy)(6-hydroxyquinolin-4-yl)methyl)-1-(2-methylbenzyl)-5-vinylquinuclidin-1-ium bromide
Cas No:
Associated Product from Buchler GmbH:
Cupreidine Base
Cas No:
70877-75-7