Asymmetric dearomative cascade multiple functionalizations of activated N-alkylpyridinium and N-alkylquinolinium salts.
DOI Number:
10.1021/acs.orglett.0c02828
Reaction Category:
MOP ID:
MOP_0000561
Educt:
substituted 1-benzylquinolin-1-ium, substituted (E)-4-(2-hydroxyphenyl)but-3-en-2-one
Product:
substituted (3aS,3a1R,8aS,13bR)-9-benzyl-3,3a,3a1,8a,9,13b-hexahydrochromeno[2,3,4-gh]phenanthridin-2(1H)-one
Catalyst:
Mandelic acid, 3-methyl-D-Valine (9S)-6′-methoxycinchonan-9-yl ester
Cas No:
2515441-80-0
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0