Organocatalytic Diastereodivergent Enantioselective Formal oxa‐Diels‐Alder Reaction of Unsaturated Ketones with Enoates Under Liquid‐Assisted Grinding Conditions.
DOI Number:
10.1002/cssc.202200028
Reaction Category:
RXNO ID:
RXNO_0000006
Educt:
enoates, unsaturated ketones
Product:
methyl (2R,3R,4S)-4-(4-methoxyphenyl)-2-(2-oxo-2-phenylethyl)-3-phenyl-3,4-dihydro-2H-pyran-6-carboxylate
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7
Associated Product from Buchler GmbH:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7