Regioselectivity Switch between Enantioselective 1,2-and 1,4-Addition of Allyl Aryl Ketones with 2,3-Dioxopyrrolidines.
DOI Number:
10.1021/acs.joc.3c01885
Reaction Category:
MOP ID:
MOP_0000562
Educt:
2,3-dioxopyrrolidines, allyl aryl ketones
Product:
substituted (S)-2-(6-benzyl-7-oxo-2,3,4,5,6,7-hexahydropyrano[2,3-c]pyrrol-2-yl)acetaldehyde
Catalyst:
3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione
Cas No:
1256245-84-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0