Enantioselective Synthesis of Tertiary α-Hydroxy Phosphonates Catalyzed by Carbohydrate/Cinchona Alkaloid Thiourea Organocatalysts.
DOI Number:
10.1002/anie.201204287
Reaction Category:
MOP ID:
MOP_0000597
Educt:
α-ketophosphonates, trimethylsilyl cyanide
Product:
tertiary α-hydroxy phosphonates
Catalyst:
N-[(8α,9S)-6′-Methoxycinchonan-9-yl]-N′-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-thiourea
Cas No:
1402349-85-2
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0