Copper-catalyzed asymmetric radical 1,2-carboalkynylation of alkenes with alkyl halides and terminal alkynes.

DOI Number:

10.1021/jacs.0c03130

Reaction Category:

Educt:

tertiary organohalogenides, primary alkynes, primary alkenes

Product:

(S)-1,3,5,5,5-pentasubstituted pent-1-yne

Catalyst:

copper(I) iodide, 2-[Bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-N-[(8α,9S)-6′-methoxycinchonan-9-yl]benzamide

Cas No:

2389028-68-4

Cas No:

130-95-0