Synthesis of quaternary-substituted thiazolines via halocyclization of S-allyl thioimidate salts.

DOI Number:

10.1021/acs.joc.7b02299
Link to literature

Reaction Category:

Chlorination | Cyclization | Cyclization | Further Cyclizations

MOP ID:

MOP_0000551

Educt:

thioimidate, 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione

Product:

(R)-4-(chloromethyl)-4-methyl-2-phenyl-4,5-dihydrothiazole

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7