Asymmetric chlorination/ring expansion for the synthesis of α-quaternary cycloalkanones.
DOI Number:
10.1021/ol5005565
Reaction Category:
MOP ID:
MOP_0000551
Educt:
substituted 1-(1-phenylvinyl)cyclobutan-1-ol, 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione
Product:
substituted (S)-2-(chloromethyl)-2-phenylcyclopentan-1-one
Catalyst:
1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)
Cas No:
140853-10-7
Associated Product from Buchler GmbH:
1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)
Cas No:
140853-10-7