An Unexpected Michael–Aldol–Smiles Rearrangement Sequence for the Synthesis of Versatile Optically Active Bicyclic Structures by Using Asymmetric Organocatalysis.
DOI Number:
10.1002/chem.200903274
Reaction Category:
Educt:
cyclohex-2-en-1-one, 1-(benzo[d]thiazol-2-ylsulfonyl)-4-phenylbutan-2-one
Product:
(1S,4S)-6-phenethylbicyclo[2.2.2]oct-5-en-2-one
Catalyst:
(8α,9S)-6′-methoxy-Cinchonan-9-amine 2,2,2-trifluoroacetate (1:2)
Cas No:
1228358-69-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0