Cinchona-Based Primary Amine-Catalyzed Asymmetric Cascade Aza-Michael–Aldol Reactions of Enones with 2-(1H-Pyrrol-2-yl)-2-oxoacetates: Synthesis of Chiral Pyrrolizines with Multistereocenters.
DOI Number:
10.1021/jo4001614
Reaction Category:
MOP ID:
MOP_0000561
Educt:
2-(1H-pyrrol-2-yl)-2-oxoacetates, enones
Product:
chiral pyrrolizines
Catalyst:
(8α,9S)-6′-(2,2-Dimethylpropoxy)cinchonan-9-amine
Cas No:
1425926-44-8
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0