Enantioselective remote C-H activation directed by a chiral cation.

DOI Number:

10.1126/science.aba1120

Reaction Category:

MOP ID:

MOP_0005000

Educt:

N-(tert-butyl)-P,P-diphenylphosphinic amides, Bis(pinacolato)diborane, hydrogen peroxide

Product:

(S)-N-(tert-butyl)-P-(3-hydroxyphenyl)-P-phenylphosphinic amides

Catalyst:

Bis[(1,2,5,6-η)-1,5-cyclooctadiene]di-μ-methoxydiiridium, (8α,9R)-10,11-dihydro-9-hydroxy-6′-methoxy-1-[[3,3′′,5,5′′-tetrakis(1,1-dimethylethyl)[1,1′:3′,1′′-terphenyl]-5′-yl]methyl]-Cinchonanium 5′-methyl[2,2′-bipyridine]-5-methanesulfonate (1:1)

Cas No:

2437404-33-4

Cas No:

522-66-7