Catalytic desymmetrization of cyclohexadienes by asymmetric bromolactonization.

DOI Number:

10.1021/ol302908a
Link to literature

Reaction Category:

Bromination | Desymmetrization | Lactonization

MOP ID:

MOP_0000551

Educt:

cyclohexadienes, N-bromsuccinimid

Product:

(3aS)-substituted (7S,7aS)-7-bromo-3a,6,7,7a-tetrahydrobenzofuran-2(3H)-one

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7