Enantioselective Bromolactonization of Conjugated (Z)-Enynes.

DOI Number:

10.1021/ja100173w

Reaction Category:

MOP ID:

MOP_0000551

Educt:

(Z)-2-(pent-2-en-4-yn-1-yloxy)benzoic acids, N-Bromosuccinimide

Product:

(S)-3-(4-bromo-3l5-buta-2,3-dien-1-yl)-2,3-dihydro-5H-benzo[e][1,4]dioxepin-5-ones

Catalyst:

N-[[[(8α,9S)-6′-Methoxycinchonan-9-yl]amino]carbonyl]-4-methylbenzenesulfonamide

Cas No:

1217548-83-8

Cas No:

130-95-0