Catalytic chemo-, regio-, diastereo-, and enantioselective bromochlorination of unsaturated systems enabled by Lewis base-controlled chloride release.
DOI Number:
10.1021/jacs.2c04588
Reaction Category:
MOP ID:
MOP_0000551
Educt:
(E)-chalcone, sulfurous dichloride, N-bromsuccinimid
Product:
(2R,3S)-2-bromo-3-chloro-1,3-diphenylpropan-1-one
Catalyst:
1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)
Cas No:
140853-10-7
Associated Product from Buchler GmbH:
1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)
Cas No:
140853-10-7