Enantioselective intermolecular bromoesterification of allylic sulfonamides.

DOI Number:

10.1039/C3SC50446H
Link to literature

Reaction Category:

Bromination

MOP ID:

MOP_0000551

Educt:

allylic sulfonamides, N-bromsuccinimid, benzoic acid

Product:

1-substituted (1R,2S)-2-bromo-3-((trifluoromethyl)sulfonamido)propyl benzoate

Catalyst:

camphorsulfonic acid, 1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7