Asymmetric Azide–Alkyne Cycloaddition with Ir (I)/Squaramide Cooperative Catalysis: Atroposelective Synthesis of Axially Chiral Aryltriazoles.
DOI Number:
10.1021/jacs.2c02563
Reaction Category:
MOP ID:
MOP_0000562
Educt:
1-(substituted-ethynyl)naphthalen-2-ol, azidoalkane
Product:
1-(1,4-substituted-1H-1,2,3-triazol-5-yl)naphthalen-2-ol
Catalyst:
3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4- [[(8α,9S)-6′-methoxycinchonan-9-yl]amino]- 3-Cyclobutene-1,2-dione
Cas No:
1256245-84-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0