Bifunctional Phase‐Transfer Catalysts Catalyzed Diastereo‐and Enantioselective Aza‐Henry Reaction of β, γ‐Unsaturated Nitroalkenes With Amidosulfones.

DOI Number:

10.1002/adsc.201700787

Reaction Category:

RXNO ID:

RXNO_0000235

Educt:

substituted tert-butyl ((phenylsulfonyl)methyl)carbamate, 2-substituted 3-nitroprop-1-ene

Product:

tert-butyl ((1S,2S)-1,3-disubstituted-2-nitrobut-3-en-1-yl)carbamate

Catalyst:

(8α,9S)-1-[[3,5-bis(1,1-dimethylethyl)phenyl] methyl]-9-[[[[(1S)-2-hydroxy-1-phenylethyl]amino]carbonyl]amino]-6′-methoxy-cinchonanium bromide

Cas No:

2095003-15-7

Cas No:

130-95-0