Highly enantioselective nitro-Mannich reaction of ketimines under phase-transfer catalysis.

DOI Number:

10.1039/C7QO00124J

Reaction Category:

RXNO ID:

RXNO_0000235

Educt:

substituted N-((6-methylpyridin-2-yl)sulfonyl)acetimidoyl, nitromethane

Product:

N-(2-substituted-1-nitropropan-2-yl)-6-methylpyridine-2-sulfonamide

Catalyst:

(8α,9S)-9-[[[[3,5-bis(trifluoromethyl)phenyl]amino]thioxomethyl]amino]-6′-methoxy-1-[(2-methoxyphenyl)methyl]-cinchonanium bromide

Cas No:

2097773-31-2

Cas No:

130-95-0