Enantio-and diastereoselective nitro-mannich reaction of α-aryl nitromethanes with amidosulfones catalyzed by phase-transfer catalysts.
DOI Number:
10.1021/acs.joc.7b00306
Reaction Category:
RXNO ID:
RXNO_0000235
Educt:
amidosulfones, α-aryl nitromethanes
Product:
tert-butyl ((1S,2R)-2-nitro-1,2-disubstituted-ethyl)carbamate
Catalyst:
(8α,9S)-1-[[3,5-bis(1,1-dimethylethyl)phenyl]methyl]-9-[[[[(1S)-2-hydroxy-1-phenylethyl]amino]carbonyl]amino]-6′-methoxy-cinchonanium bromide
Cas No:
2095003-15-7
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0