Catalytic Enantioselective Synthesis of Atropisomeric Biaryls: A Cation‐Directed Nucleophilic Aromatic Substitution Reaction.

DOI Number:

10.1002/anie.201408205

Reaction Category:

Educt:

2,6-disubstituted 4,6-dichloro-5-phenylpyrimidine, benzenethiol

Product:

2,6 disubstituted (r)-4-chloro-5-phenyl-6-(phenylthio)pyrimidine

Catalyst:

9-hydroxy-6′-methoxy-1-(phenylmethyl)-cinchonanium chloride

Cas No:

67174-25-8

Cas No:

67174-25-8