Catalytic, asymmetric α-fluorination of acid chlorides: dual metal− ketene enolate activation.
DOI Number:
10.1021/ja807792c
Reaction Category:
MOP ID:
MOP_0000553
Educt:
acid chlorides, N-fluorbenzolsulfonimid, methanol
Product:
methyl (R)-2-fluoro-2-(4-methoxyphenyl)acetate
Catalyst:
Dichloro[1,1′-(1,3-propanediyl)bis[1,1-diphenylphosphine-κP]]nickel, 6′-methoxy-(9S)-Cinchonan-9-ol-9-benzoate
Cas No:
60723-45-7
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2