Enantioselective allylic amination of Morita–Baylis–Hillman carbonates catalysed by modified cinchona alkaloids.

DOI Number:

10.1002/ejoc.200900944
Link to literature

Reaction Category:

Allylic Amination | Amination

Educt:

naphthalin-1,8-dicarboximid, Morita–Baylis–Hillman carbonates

Product:

methyl (R)-2-((1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)(4-methoxyphenyl)methyl)acrylate

Catalyst:

(9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)] bis[10,11-dihydro-6′-methoxy-cinchonan]

Cas No:

149725-81-5

Associated Product from Buchler GmbH:

Dihydroquinidine Base

Cas No:

1435-55-8