Vinylogous Nucleophiles Bearing the Endocyclic Double Bond in the Allylic Alkylation with Morita-Baylis-Hillman Carbonates.

DOI Number:

10.1002/adsc.201701185

Reaction Category:

MOP ID:

MOP_0000369

Educt:

6-chloro-4-methyl-2-oxo-2H-chromene-3-carbonitrile, methyl 2-(((tert-butoxycarbonyl)oxy)(phenyl)methyl)acrylate

Product:

methyl (R)-4-(6-chloro-3-cyano-2-oxo-2H-chromen-4-yl)-2-methylene-3-phenylbutanoate

Catalyst:

(1S,1'S,3R,3'R,4S,4'S,6R,6'R)-6,6'-((1S,1'S)-((2,5-diphenylpyrimidine-4,6-diyl)bis(oxy))bis((6-methoxyquinolin-4-yl)methylene))bis(3-ethylquinuclidine)

Cas No:

149725-81-5

Cas No:

1435-55-8