Highly enantioselective phase transfer catalyzed alkylation of a 3-oxygenated propionic ester equivalent; applications and mechanism.
DOI Number:
10.1021/ja9835739
Reaction Category:
MOP ID:
MOP_0000369
Educt:
tert-butyl 4,4-bis(4-(dimethylamino)phenyl)but-3-enoate, allylbromide
Product:
tert-butyl (R)-2-(2,2-bis(4-(dimethylamino)phenyl)vinyl)pent-4-enoate
Catalyst:
(8α,9R)-1-(9-anthracenylmethyl)-9- (2-propenyloxy)-Cinchonanium bromide
Cas No:
200132-54-3
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2