Chiral phosphine-free Pd-mediated asymmetric allylation of prochiral enolate with a chiral phase-transfer catalyst.
DOI Number:
10.1021/ol016567h
Reaction Category:
MOP ID:
MOP_0000369
Educt:
tert-butyl 2-((diphenylmethylene)amino)acetate, trans-substituted allyl acetate
Product:
trans-substituted tert-butyl (S)-2-((diphenylmethylene)amino)pent-4-enoate
Catalyst:
triphenyl phosphite, di-μ-chlorobis(η3-2-propenyl)di-palladium, 1-(9-anthracenylmethyl)-9-methoxy-(1S,9R)-cinchonanium iodide
Cas No:
374562-79-5
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2