Latent Pronucleophiles in Lewis Base Catalysis: Enantioselective Allylation of Silylated Stabilized Carbon Nucleophiles with Allylic Fluorides.

DOI Number:

10.1002/chem.202300641
Link to literature

Reaction Category:

Alkylation | Allylation

MOP ID:

MOP_0000369

Educt:

allylic fluorides, silylated stabilized carbon nucleophiles

Product:

5-substituted methyl (R)-3-(2-fluorophenyl)-2-methylene-5-oxopentanoate

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7