Enantio-and diastereodivergent dual catalysis: α-allylation of branched aldehydes.
DOI Number:
10.1126/science.1237068
Reaction Category:
MOP ID:
MOP_0000369
Educt:
2-phenylpropanal, 1-phenylprop-2-en-1-ol
Product:
(2R,3R)-2-methyl-2,3-diphenylpent-4-enal
Catalyst:
dichlorobis(cyclooctadiene)di-iridium, 5-(dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-5H-dibenzo[b,f]azepine, (9R)-Cinchonan-9-amine
Cas No:
168960-96-1
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5