Organocatalytic asymmetric conjugate additions to cyclopent-1-enecarbaldehyde: a critical assessment of organocatalytic approaches towards the telaprevir bicyclic core.
DOI Number:
10.1002/chem.201503352
Reaction Category:
MOP ID:
MOP_0000369
Educt:
tert-butyl 2-((diphenylmethylene)amino)acetate, cyclopent-1-ene-1-carbaldehyde
Product:
tert-butyl (S)-2-((diphenylmethylene)amino)-2-((1S,2R)-2-formylcyclopentyl)acetate and tert-butyl (S)-2-((diphenylmethylene)amino)-2-((1S,2S)-2-formylcyclopentyl)acetate
Catalyst:
(8α,9R)-1-(9-anthracenylmethyl)-9- (2-propenyloxy)-Cinchonanium bromide
Cas No:
200132-54-3
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2