A new family of cinchona-derived amino phosphine precatalysts: application to the highly enantio-and diastereoselective silver-catalyzed isocyanoacetate aldol reaction.
DOI Number:
10.1021/ja110534g
Reaction Category:
RXNO ID:
RXNO_0000016
Educt:
methyl 2-isocyano-2-phenylacetate, 3-fluorobenzaldehyde
Product:
methyl (4R,5R)-5-(3-fluorophenyl)-4-phenyl-4,5-dihydrooxazole-4-carboxylate
Catalyst:
silver(I) oxide, N-[(9R)-10,11-dihydrocinchonan-9-yl]-2-(diphenylphosphino)-benzamide
Cas No:
1263322-12-8
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8