Enantioselective Sulfonimidamide Acylation via a Cinchona Alkaloid-Catalyzed Desymmetrization: Scope, Data Science, and Mechanistic Investigation.
DOI Number:
10.1021/jacs.4c00374
Reaction Category:
MOP ID:
MOP_0000479
Educt:
benzenesulfonimidamide, 2,2,2-trifluoroethyl 2,2,2-trifluoroacetate
Product:
(S)-N-(amino(oxo)(phenyl)-sulfaneylidene)-2,2,2-trifluoroacetamide
Catalyst:
(8α,9R)-6′-methoxy-, 9-[P,P-bis(4-methoxyphenyl)phosphinate]cinchonan-9-ol
Cas No:
3027633-19-5
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0