Stereodivergence in amine-catalyzed regioselective [4+2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles.

DOI Number:

10.1021/ja3106219
Link to literature

Reaction Category:

[4+2]-Cycloaddition | Cycloaddition | Diels-Alder reaction

MOP ID:

MOP_0000565

Educt:

beta-substituted cyclic enones, polyconjugated malononitriles

Product:

substituted (1R,3S,4R)-1-methyl-5-oxo-3-((E)-prop-1-en-1-yl)bicyclo[2.2.2]octane-2,2-dicarbonitrile

Catalyst:

(9R)-6′-methoxy-cinchonan-9-amine

Cas No:

287979-82-2

Associated Product from Buchler GmbH:

Quinidine Base

Cas No:

56-54-2