Cooperative organocatalysis for the asymmetric γ alkylation of α‐branched enals.
DOI Number:
10.1002/anie.201004761
Reaction Category:
MOP ID:
MOP_0000369
Educt:
α‐branched enals, 4,4′-Bis(dimethylamino)benzhydrol
Product:
(R,E)-4-benzyl-5,5-bis(4-(dimethylamino)phenyl)-2-methylpent-2-enal
Catalyst:
(S)-2,2′-Dihydroxy-3,3′-bis(4-nitrophenyl)-1,1′-binaphthalene cyclic phosphate, (9R)-9-Aminocinchonan-6′-ol
Cas No:
960050-60-6
Associated Product from Buchler GmbH:
Cupreidine Base
Cas No:
70877-75-7