Free radical-mediated aryl amination: a practical synthesis of (R)- and (S)-7-azaindoline α-amino acid.

DOI Number:

10.1055/s-2004-831226
Link to literature

Reaction Category:

Alkylation | Alkylation

MOP ID:

MOP_0000369

Educt:

tert-butyl 2-((diphenylmethylene)amino)acetate, 3-bromo-2-(bromomethyl)pyridine

Product:

tert-butyl (R)-3-(2-bromopyridin-3-yl)-2-((diphenylmethylene)amino)propanoate

Catalyst:

(9S)-1-(9-anthracenylmethyl)-9-(2-propenyloxy)-Cinchonanium bromide

Cas No:

219601-70-4

Associated Product from Buchler GmbH:

Cinchonine Base

Cas No:

118-10-05