Highly Enantioselective Synthesis of α-Diazo-β-hydroxy Esters Using a Bifunctional Titanium Complex.

DOI Number:

10.1055/s-0029-1217322
Link to literature

Reaction Category:

Aldol | Aldol

RXNO ID:

RXNO_0000016

Educt:

aldehydes, ethyl 2-diazoacetate

Product:

alpha-diazo-beta-hydroxy esters

Catalyst:

(S)-BINOL, Tetraisopropyl Titanate, Quinidine Base

Cas No:

56-54-2

Associated Product from Buchler GmbH:

Quinidine Base

Cas No:

56-54-2