A Highly Stereoselective Hydrogen‐Bond‐Mediated Michael–Michael Cascade Process through Dynamic Kinetic Resolution.

DOI Number:

10.1002/anie.200800381

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

substituted ethyl (E)-3-(2-mercaptophenyl)acrylates, nitroolefins

Product:

substituted thiochromanes

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′- [(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7