N-2-Iodobenzylcinchoninium bromide is effective for catalytic enantioselective trifluoromethylation of azomethine imines in Solkane® 365mfc.

DOI Number:

10.1016/j.jfluchem.2012.06.008

Reaction Category:

MOP ID:

MOP_0000368

Educt:

azomethine imines, trimethyl(trifluoromethyl)silane

Product:

substituted (S)-1-(1-aryl-2,2,2-trifluoroethyl)pyrazolidin-3-one

Catalyst:

9-hydroxy-1-[(2-iodophenyl)methyl]-(9S)-Cinchonanium bromide (1:1)

Cas No:

1410875-87-4

Cas No:

118-10-5