Organocatalytic Asymmetric Fluorination/Semipinacol Rearrangement: An Efficient Approach to Chiral β-Fluoroketones.
![](https://www.buchler-gmbh.com/wp-content/uploads/Fluorination-5.jpg)
DOI Number:
10.1002/chem.201202444
Reaction Category:
MOP ID:
MOP_0000553
Educt:
2-oxa allylic alcohols, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide
Product:
beta-fluoro ketones
Catalyst:
(8α,9R)-(8′′α,9′′R)-9,9′′-[(2,5-Diphenyl-4,6-pyrimidinediyl)bis(oxy)] bis[10,11-dihydro-6′-methoxycinchonan]
Cas No:
149820-65-5
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7