Asymmetric supramolecular catalysis: a bio-inspired tool for the high asymmetric induction in the enamine-based Michael reactions.

DOI Number:

10.1002/chem.201200962

Reaction Category:

MOP ID:

MOP_0000561

Educt:

cyclohexanone, substituted (E)-2-(2-nitrovinyl)phenol

Product:

substituted (4aS,9R,9aS)-9-(nitromethyl)-2,3,4,4a,9,9a-hexahydro-1H-xanthene

Catalyst:

D-Proline, N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7