Asymmetric construction of axially chiral 2‐arylpyrroles by chirality transfer of atropisomeric alkenes.
DOI Number:
10.1002/anie.201907470
Reaction Category:
Educt:
atropisomeric alkenes, (3-bromoprop-1-yn-1-yl)trimethylsilane
Product:
chiral 2‐arylpyrroles
Catalyst:
(9S)-2′-[3,5-bis(1,1-dimethylethyl)phenyl]-9-[[3,5-bis(trifluoromethyl)phenyl]methoxy]-1-[(3,4,5-trifluorophenyl)methyl]-cinchonanium bromide
Cas No:
2376632-12-9
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5