Bicarbonate-binding catalysis for the enantioselective desymmetrization of keto sulfonium salts.

DOI Number:

10.1038/s41467-024-48832-x
Link to literature

Reaction Category:

Desymmetrization

Educt:

keto sulfonium salts

Product:

(R,E)-5-(methylthio)-1,5-diphenylpent-1-en-3-one

Catalyst:

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[(9R)-cinchonan-9-ylamino]-3-cyclobutene-1,2-dione

Cas No:

1256245-82-5

Associated Product from Buchler GmbH:

Cinchonine Base

Cas No:

118-10-5